Abstract

Large-area and uniform plasmonic nanostructures have often been fabricated by simply evaporating noble metals such as gold and silver on a variety of nanotemplates such as nanopores, nanotubes, and nanorods. However, some highly uniform nanotemplates are limited to be utilized by long, complex, and expensive fabrication. Here, we introduce a cost-effective and high-throughput fabrication method for plasmonic interference coupled nanostructures based on quasi-uniform anodic aluminum oxide (QU-AAO) nanotemplates. Industrial aluminum, with a purity of 99.5%, and copper were used as a base template and a plasmonic material, respectively. The combination of these modifications saves more than 18 h of fabrication time and reduces the cost of fabrication 30-fold. From optical reflectance data, we found that QU-AAO based plasmonic nanostructures exhibit similar optical behaviors to highly ordered (HO) AAO-based nanostructures. By adjusting the thickness of the AAO layer and its pore size, we could easily control the optical properties of the nanostructures. Thus, we expect that QU-AAO might be effectively utilized for commercial plasmonic applications.

Highlights

  • Plasmonic nanostructures are critically promising for next-generation optical devices such as displays and optical sensors [1,2,3,4,5,6,7,8]

  • We found that quasi-uniform anodic aluminum oxide (QU-Anodic aluminum oxide (AAO)) based plasmonic nanostructures exhibit similar optical behaviors to highly ordered (HO) AAO-based nanostructures

  • While achieving similar optical properties as the traditional method based on highly ordered AAO (HO-AAO) templates, we are able to significantly reduce the total fabrication time and cost

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Summary

Introduction

Plasmonic nanostructures are critically promising for next-generation optical devices such as displays and optical sensors [1,2,3,4,5,6,7,8]. Previous fabrication techniques for large-area plasmonic structures are limited by being high in cost, with low throughput and low reproducibility [14,15,16]. To overcome these disadvantages, template-based lithography for large-area uniform plasmonic nanostructures has been developed, but the large-area uniform template fabrications still are high in cost and their throughputs are very low [17,18,19,20]. The periodic nanoarrays are excellent platforms for biosensing applications [28,29] Noble metals such as gold and silver, deposited on AAO nanopores, for instance, form hotspots in surface-enhanced Raman spectroscopy (SERS) measurement. With an improved AAO fabrication, high SERS sensitivity (i.e., a detection limit of ~fM) has been recently demonstrated [30,31,32,33,34]

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