Abstract
A novel silane-functional polybenzoxazine (PB-TMOS) coating, with silane groups that can bond to the substrate, was prepared through a dip-coating and thermal curing method. The coating properties were investigated by Fourier transform infrared spectroscopy, solid-state nuclear magnetic resonance spectroscopy, static contact angle measurement, electrochemical and accelerated corrosion tests. The corrosion resistant performance of PB-TMOS coated specimens was considerably enhanced by the high hydrophobicity and water resistance resulted from the dual cross-linking network of polybenzoxazine and Si–O–Si in PB-TMOS matrix.
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