Abstract

The corrosion of refractories constitutes a high-temperature process of solid phase dissolution in the melts. Dissolution is a physico-chemical process with changing chemical composition of the solid and liquid phase. The liquid layer, which is in contact with the surface of the solid phase, is enriched by dissolved matter. This leads to changes in the structure of the melt and also changes to the physical properties in the contact layer, which evokes both vertical and horizontal hydro-dynamical flow in the melt in an effective diffusion layer and this process consequently creates a solid-phase corrosion profile.

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