Abstract

Alumina coatings are widely used to enhance the wear, abrasion, and corrosion resistance of metal components. This investigation aims at studying the alumina sol-gel coating on the anodized aluminum alloy surface using a dip coating technique. A stable alumina coating was deposited over the anodized aluminum surface using oxime-modified aluminum(III) isopropoxide as sol-gel precursor. The scanning electron microscopy image of the coated anodized sample suggests deposition of a uniform and crack-free aluminum coating. The corrosion resistances of bare, anodized, and coated anodized aluminum alloy samples were investigated by electrochemical impedance spectroscopy and potentiodynamic polarization in 3.5 wt % aqueous NaCl solution. An appreciable shifting was observed in the equilibrium corrosion potential (Ecorr) and the corrosion current density (icorr) values of both anodized and coated anodized samples: i.e. Ecorr: from –1377.11 mV (anodized) to –711.54 mV (coated anodized) and icorr: from 80.37 μA/cm2 (anodized) to 0.090 μA/cm2 (coated anodized). The results clearly indicate the corrosion resistive behavior of nano-alumina coatings.

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