Abstract

In this work, a cement-bonded corundum-spinel (Al 2 O 3 –MgAl 2 O 4 ) pre-cast refractory brick with two typical Al 2 O 3 aggregates was designed as the refractory lining. Corroded microstructure of the used corundum-spinel bricks after industrial trials in a commercial RH refining ladle was analyzed. Degradation processes of two types of alumina aggregates in the same corroded interface also were discussed. Typical corroded microstructure revealed that needle-like calcium hexaaluminate (CA 6 ) was observed in the matrix of the original layer. The formation of CA 6 was attributed to the reactions with pure calcium aluminate cement and matrix components under a high-temperature gradient during refining. Furthermore, the corrosion process of the used Al 2 O 3 –MgAl 2 O 4 bricks would be discussed based on a post-mortem microstructural characterization, and the corrosion mechanism of the two types of aggregates was also elucidated.

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