Corrosion Evaluation and Inhibiting Effect of Chlorpheniramine Drug on Mild Steel in HCl Acid

Abstract

The importance of non harmful inhibitors has informed the application of drugs as an agent to mitigate corrosion of metal materials. This research reveals the inhibitive reaction and adsorption mechanism of Chlorpheniramine drug (CD), on mild steel in an HCl solution using Potentiodynamic polarization, open circuit potential and weight loss method. The CD inhibitor was proportioned into 2.5, 5, 7.5, and 10ml while molarity of HCl was varied in the proportion of 0.1, 0.5, 1.0 and 1.5M at a temperature of 298 K. The reaction showed that as the CD concentration moves to higher concentration, the efficiency of the inhibitor increases, also the higher the concentration of the acid, the higher the corrosion rate. Observation from the result revealed that CD inhibitor protected the steel from corrosion destruction. The optimum efficiency occurred as 85.80% at 10ml CD concentration. CD inhibitor obeyed Freundlich law of isotherm with the average regression value of R2 = 0.9733, as R2 value gets close to unity. Scanning Electron Microscopy (SEM) and Energy-dispersive X-ray spectra (EDX) results also confirm strong adsorption mechanisms of CD inhibitor on the mild steel samples. Keywords: Chlorpheniramine Drug; Green Inhibitor; Open circuit potential; Potentiodynamic Polarization; Mild steel