Corrosion control of Cu–Ni alloys in neutral chloride solutions by amino acids

Abstract

The corrosion inhibition of Cu–Ni alloys was investigated in aqueous chloride solutions using amino acids as environmentally safe materials. The corrosion rate was calculated in absence and presence of the corrosion inhibitor using polarization and impedance techniques. The inhibition efficiency of the different amino acids was also calculated. The experimental results have shown that a simple amino acid like glycine can be used as efficient corrosion inhibitor for the Cu–Ni alloys in neutral chloride solutions. An inhibition efficiency of about 85% could be achieved at very low concentrations of the amino acid (0.1 mM). For low Ni content alloy (Cu–5Ni), 2.0 mM cysteine shows a remarkable high (∼96%) corrosion inhibition efficiency. The experimental impedance data were fitted to theoretical data according to a proposed equivalent circuit model for the electrode/electrolyte interface, and the mechanism of the corrosion inhibition process was suggested. Different adsorption isotherms were tested and the corrosion inhibition process was found to depend on the adsorption of the amino acid molecules and/or the deposition of corrosion products on the alloy surface. The adsorption free energy of cysteine on Cu–5Ni (−37.81 kJ mol −1) reveals a strong physical adsorption of the inhibitor on the alloy surface.