Corrosion Characteristics and Mechanical Properties of Inconel 622 Weld Overlay of Waterwall Tubes in Coal Fired Boilers

Abstract

Recently in Japan, boiler waterwall tube damage such as fireside corrosion and circumferential cracking in a low NOx environment has become a serious issue, despite the fact that relatively lower sulfur content coal is typically being used than in the US. Thermal spray coating is the most popular method for tube protection in Japan, and thermal spray coating tubes are used for this purpose.However, extensive damage to thermal spray coating tubes from cracking and exfoliation has recently been experienced. It is reported that the thermal fluctuations that occur as a result of operating changes create alternating stress, leading to cracking and exfoliation of the thermal sprayed thin coating. Corrosion-resistant weld overlays, such as stainless steel type 309, alloy 625 and alloy 622, are now commonly used to protect corrosion of boiler tubes in low NOx coal fired boilers in the US. In order to develop a fundamental understanding of the high temperature corrosive behavior of alloy 622 weld overlay, gaseous corrosion testing and certain mechanical tests for consideration of long-term aging were undertaken. After one year of service in the low NOx combustion environment of a coal fired supercritical boiler, field tests on alloy 622 weld overlay panels are continuing.This report describes the behavior of alloy 622 overlay panels in a field test installed in a Japanese supercritical boiler, the laboratory results of weight loss corrosion testing, and mechanical tests related to aging.