Corrosion behavior of SM 80SS tube steel in stimulant solution containing H 2S and CO 2

Abstract

Scanning electron microscopy, X-ray diffraction and electrochemical measurement technique were applied to investigate the corrosion of SM 80SS tube steel in stimulant solution with carbon dioxide (CO 2) and hydrogen sulfide (H 2S) at variable conditions of P C O 2 / P H 2 S and temperature. The results suggest that there exists a synergism of sweet corrosion and sour corrosion on the steel surface, corrosion attack increases in the initial stage and then decrease with the increase of P C O 2 or P H 2 S ; serious corrosion occurs in the P C O 2 / P H 2 S ranged from 31 to 520. In addition, the fitted parabola function equation Y = 0.47873 + 0.04014 X – (3.23788E−5) X 2 is established, and the most serious corrosion is 600 for P C O 2 / P H 2 S . Under the moderate contents of P C O 2 and P H 2 S , the corrosion scale consists of FeS 0.9 and FeCO 3; for relatively high P H 2 S , additive product FeS comes into being at high temperature such as T = 150 °C, product FeO(OH) is found in the corrosion scale. The H 2S corrosion has a significant effect on the whole reaction process and iron sulfide is superior to precipitating on the steel surface compared with iron carbonate. In addition, the surface scales of iron sulfide almost act as a diffusion barrier and inhibit the corrosion by a coverage effect strongly depending on H 2S concentration by EIS measurement.