Corrosion behavior of electrodeposited Co-Fe alloys in aerated solutions

Abstract

Co-Fe alloy is an important component for reader-writer in hard disk drive. The surface of the alloy is exposed to the environment both in gas phase and in liquid phase during manufacturing process. The study of corrosion behavior of Co-Fe alloys can provide useful fundamental data for reader-writer production planning especially when corrosion becomes a major problem. The corrosion study of electrodeposited Co-Fe alloys from cyclic galvanodynamic polarization was performed using potentiodynamic polarization technique. The composition of electrodeposited Co-Fe alloys was determined by X-ray fluorescence spectrometry. The patterns from X-ray diffractometer showed that the crystal structure of electrodeposited Co-Fe alloys was body-centered cubic. A vibrating sample magnetometer was used for magnetic measurements. The saturation magnetization (Ms) was increased and the intrinsic coercivity (Hci) was decreased with increasing Fe content. The corrosion rate study was performed in aerated deionized water and aerated acidic solutions at pH 3, 4 and 5. The corrosion rate diagram for Co-Fe alloys was constructed. It was found that the corrosion rate of Co-Fe alloys was increased with increasing Fe content in both aerated deionized water and aerated acidic solutions. In aerated pH 3 solution, the Co-Fe alloy containing 78.8% Fe showed the highest corrosion rate of 7.7mmyr−1 with the highest Ms of 32.0Am2kg−1. The corrosion rate of the alloy with 23.8% Fe was at 1.1mmyr−1 with Ms of 1.2Am2kg−1. In aerated deionized water, the alloy with the highest Fe content of 78.5% still showed the highest corrosion rate of 0.0059mmyr−1 while the alloy with the lowest Fe content of 20.4% gave the lowest corrosion rate of 0.0045mmyr−1.