Corrosion and passivation behavior of Mg–Zn–Y–Al alloys prepared by cooling rate-controlled solidification

Abstract

Highly corrosion-resistant nanocrystalline Mg–Zn–Y–Al multi-phase alloys have been prepared by consolidation of rapidly solidified (RS) ribbons. The relation between corrosion behavior and microstructure evolution of Mg–Zn–Y–Al alloys with a long period stacking ordered phase has been investigated. In order to clarify the influence of rapid solidification on the occurrence of localized corrosion such as filiform corrosion, several Mg 96.75Zn 0.75Y 2Al 0.5 (at.%) alloys with different cooling rates are fabricated by the gravity casting, copper mould injection casting and melt-spinning techniques and their corrosion behavior and microstructures are examined by the salt water immersion test, electrochemical measurements, GDOES, XRD, SEM and TEM. To clarify the effect of aluminium addition on the improvement in corrosion resistance of the alloys, several Mg 97.25− x Zn 0.75Y 2Al x alloys with different aluminium contents are fabricated by consolidating RS ribbons and the formation of corroded films on the Mg–Zn–Y–Al alloys have been investigated. Rapid solidification brings about the grain refinement and an increase in the solid solubility of zinc, yttrium and aluminium into the magnesium matrix, enhancing microstructural and electrochemical homogeneity, which in turn enhanced corrosion resistance. The addition of aluminium to magnesium can modify the structure and chemical composition of surface films and improves the resistance to local breakdown of the films.