Corrosion analysis and performance investigation of hybrid MXene/C-dot Nanofluid-Based direct absorption solar collector

Abstract

Nanofluids having exceptional thermo-optical characteristics can enhance the performance of direct absorption solar collectors (DASC). Conventional nanofluids have either high optical properties or thermal properties. In this study, carbon quantum dot (C-dot) nanomaterial with high stability and optical absorption along the UV range, and MXene nanoparticles with high thermal conductivity and absorption along visible and near-infrared (NIR) spectral range was selected for synthesizing a hybrid nanomaterial with synergistic thermo-optical properties. Hybrid MXene/C-dot nanofluid exhibits higher stability, thermal conductivity, and complementary absorption properties of individual nanomaterials. A two-step method was used for the synthesis of nanofluids using water as the base fluid. Thermal conductivity, UV–Vis-NIR spectroscopy, and stability analysis were conducted on nanofluids, and the concentration was optimized for corrosion study and application in direct absorption parabolic trough collector (DAPTC). Optimised concentrations of C-dot, MXene, and hybrid nanofluids were 0.15 wt%, 0.1 wt% and 0.15 wt%, respectively. The corrosion study states that copper electrodes dipped in the hybrid nanofluid exhibited the least corrosion rate of 0.6 mm/year with an anticorrosion efficiency of 64.5 % over DI water. Thermal efficiency and entropy generation in the system with different HTFs were measured and compared with that of the base fluid. The study shows that C-dot and MXene/C-dot nanofluids were producing the highest efficiencies of 50.5 % and 47.5 % at a flow rate of 1.2 lpm. This study shows that hybrid MXene/C-dot nanofluid exhibited exceptional thermal stability, reduced corrosion effects, and considerable enhancement in photothermal conversion efficiency of the DASC.