Corrigendum: Multiple Multidentate Halogen Bonding in Solution, in the Solid State, and in the (Calculated) Gas Phase.

Abstract

In the Full Paper, superfluous text was included in the list on page 13629 at the final stages. The editorial office apologizes for this mistake. The correct paragraph should read as follows: Summary of crystallization studies In summary, we were able to obtain ten crystal structures, nine of which are XB-based adducts of XB donors p-/m-1 and 2 with halides showing a variety of different binding patterns: • In case of quaterphenyl derivative 2, all three crystal structures show the same pentadentate binding of one anion by two XB donor molecules (3&2 motif). • Identical, tridentate (2&1 motif) binding of each anion was obtained for p-1⋅Br, m-1⋅Cl, and m-1⋅Br. In these cases, one CI bond does not participate in any non-covalent interaction. • A slightly different structure was observed for p-1⋅Cl, in which every iodo substituent forms an XB to chloride, bidentate on one side of the XB donor and twofold monodentate on the other side (2&1+1 motif). This results in a branched coordination polymer. The 3&2 and 2&1 coordination patterns of the structures addressed so far result from a slight distortion of the central benzene core. This leads to the formation of as many XB as possible on one side of the donor and one less XB on the opposing side. • When iodide is used as XB acceptor, the adducts of terphenyl-based XB donors p-/m-1 display a tetradentate (2&2 motif) binding pattern. Adduct m-1⋅I is a linear polymer, whereas p-1⋅I forms a zigzag binding pattern.