Abstract

Energy levels, fine and hyperfine structure, as well as E1 transition amplitudes in thallium and gold, are calculated. Application of the relativistic Hartree-Fock equations, taking into account electron shell polarisation and correlation corrections to the wavefunction, provides an accuracy of the order of a few per cent as a rule. This is an order of magnitude better than the accuracy of simple Hartree-Fock calculations. An estimate for structural radiation is made.

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