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Abstract
The UNIQUAC associated-solution model is used to correlate the spectroscopic and thermodynamic properties of solutions of ethanol in a non-associating component in terms of three self-association constants of open-chain hydrogen-bonded groups, one self-association constant of cyclic groups and one enthalpy for formation of the hydrogen bonds. This model gives a better prediction of the vapour-liquid equilibrium and excess enthalpy than the association model of Nagata and Tamura for ternary solutions of ethanol with two non-associating components.
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