Abstract
A model-correlating structure with gas chromatographic retention index was developed to assist in making positional isomer assignments for dioxins halogenated by bromine and/or chlorine using commercially available standards and synthetic mixtures. Bromodibenzofuran assignments were made using pyrolysate mixtures, assuming the elution order was the same as for chlorinated dibenzofurans. These strategies can be used, on an interim basis, for isomer assignments in environmental monitoring efforts.
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