Abstract
Oxygen-deficient spinel (LiMn) 3O 4− z was successfully synthesized by melt-impregnation method. The chemical composition of each spinel sample was carefully analyzed and the value of z was correlated with its discharge capacity at about 3.2 V ( C 3.2V). The linear relationship between C 3.2V and z was theoretically deduced from the structural consideration of (LiMn) 3O 4− z .
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