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Abstract
The secondary α-deuterium isotope effect in iodide-131 exchange of methyl-d3 iodide is kH/kD = 1.05 ± 0.01 in methanol and 1.10 ± 0.04 in water at 20°. A correlation of secondary α-deuterium and 13C effects, in bimolecular nucleophilic substitution reactions, with the difference of E values between nucleophile and leaving group is presented.
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