Abstract
Liquid-vapor phase equilibria in binary systems formed by haloarenes were studied. The contributions of intermolecular interactions to the thermodynamic functions of liquid haloarenes and their binary solutions were calculated. The contributions of intermolecular interactions to the Helmholtz energy of binary solutions of constant molar concentrations formed by fluoroarene and haloarenes were found to depend linearly on the molecular weight of haloarenes. The corresponding correlation equations were suggested.
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