Correlation between Si-Al disorder and hydrogen-bonding distance variation in ussingite (Na2AlSi3O8OH) revealed by one- and two-dimensional multi-nuclear NMR and first-principles calculation

Abstract

Abstract Ussingite (Na2AlSi3O8OH) is a mineral with a unique interrupted framework structure and strong hydrogen bonding. It contains 4-, 6-, and 8-membered tetrahedral rings resembling feldspars, but, unlike the latter, is partially depolymerized. There are four crystallographically distinct tetrahedral (T) sites, two of which (T1, T2) are Q4 [i.e., having 4 next nearest neighbor (NNN) T sites], and the other two (T3, T4) are Q3 (i.e., having 3 NNN T sites), each with NNN (in brackets) of T1(1T2, 1T3, 2T4), T2(1T1, 2T3, 1T4), T3(1T1, 2T2), and T4(2T1, 1T2). There is one unique OH site in the T4-O8-H···O2-T3 configuration, where O8 and O2 are nonbridging O atoms (NBO). In the ordered structure, T1 is fully occupied by Al, and the other three T sites by Si. Previous X-ray and neutron diffraction and 1H and 29Si NMR studies gave contradictory conclusions regarding Si-Al disorder. In this study, we were able to unambiguously clarify the issue via comprehensive one- and two-dimensional 1H, 29Si, 27Al, and 23Na NMR and first-principles calculation. It was revealed that there is ~3% Si-Al disorder that occurs between neighboring T1-(O)-T2 sites, such that the formation of Al-O-Al linkage and Al(Q3) are avoided. The disorder was found to result in the development of Si(Q3) sites with various NNN, including 3Al and 3Si, and neighboring OH sites having significantly shorter and longer hydrogen-bonding distances than in the ordered structure, with 1H chemical shifts near 15~16 ppm and 11 ppm, in addition to a main peak near 13.9 ppm. Good correlation was found between 1H chemical shift, hydrogen-bonding (O-H, H···O, and O···O) distances, and Si-O distances in the Si-O-H···O-Si linkage. This suggests that Si-Al disorder is correlated with variation in hydrogen-bonding distances via through-bond transmission of bond valence variations. This could be a universal phenomenon also applicable to other hydrous minerals. The revelation of preferential partition of Al in Q4 over Q3 sites to avoid the formation of Al-OH and Al-NBO provides insight into their behavior in other partially depolymerized hydrous aluminosilicate systems, such as glasses and melts.