Correlation between physical, optical and structural properties of sulfide glasses in the system Ge–Sb–S

Abstract

Germanium-based sulfide glasses in the Ge–Sb–S system have been elaborated and studied. A relationship between the structure, the composition and the linear optical properties of the glass has been established. The effects of the introduction of Sb on the structure using IR and Raman spectroscopies and on the linear refractive index have been discussed. We have shown that the progressive introduction of Sb 2S 3 in the glass system (1 − x)GeS 2– xSb 2S 3 (with x = 0.10, 0.20, 0.40, 0.62 and 0.80) decreases the number of GeS 4 units in the glass network. As results, the glass transition temperature, the Vicker's microhardness and the stability of the glass against crystallization decrease dramatically. An increase in the density and the linear refractive index as well as shift of the absorption bandgap to infrared have also been observed. Similar behavior has been observed for the glasses of composition Ge 0.23Sb y S 0.77− y with an increase of y, except in the material's Vicker's microhardness, which increases with an increasing Sb content. This latter result indicates that the microhardness also depends on Sb 2S 3 content but seems to be more sensitive to GeS 2 content variation.