Correlation between mechanical properties and pore structure deterioration of recycled concrete under sulfate freeze-thaw cycles: an experimental study

Abstract

Concrete is subject to the combined erosive effects of physical and chemical activities in cold, salty soil regions. In this work, durability tests of recycled concrete (RC) subjected to sulfate freeze-thaw cycles were conducted. The macroscopic performance deterioration law of RC under the influence of the replacement rate (0%, 50%, 100%) and the moisture content of coarse recycled concrete aggregate (CRCA) (0%, 50%, 100%) was investigated by analyzing the change characteristics of apparent damage, mass loss rate, and Relative dynamic modulus of elasticity (RDME) of RC during the erosion process. At the same time, nuclear magnetic resonance (NMR) and microhardness testing equipment were used to examine the multi-parameter evolution features such as porosity, pore distribution, interfacial transition zone (ITZ) width, and strength. The findings indicate that the main cause of the variation in the degree of damage to the RC surface layer is the variance in the effective water-cement (w/c) ratio of the mortar due to replacement rate and moisture content. The strength and area of erosion damage increase when the CRCA replacement rate rises due to the easier inward penetration of the sulfate solution. CRCA with a 50% moisture content could increase the strength of the mortar by decreasing the mortar's effective w/c ratio. The rate and effectiveness of salt solution replenishment inward were simultaneously slowed down by the improved ITZ performance. In erosive situations, the fractal dimension of RC reduces to varying degrees. This is due to the expansion of the pore structure. The porosity/fractal dimension is employed as the comprehensive pore parameter η in this research so as to take into account the integrity of the pore structure and the specificity of the pore distribution. The improved microstructure damage variables can reflect the erosive microstructure deterioration process of RC.