Abstract

The present work investigates the influence of donor doping and its concentration on the flash sintering behavior of barium titanate. The characteristic of non-ohimic conductivity during flash event shows that flash sintering is associated with dielectric breakdown due to the similar physical phenomena. The polarization of dielectric particle contributes to the enhancement of local electric field strength. The magnified electric field caused by local charges accumulation gives rise to dielectric breakdown phenomenon during flash sintering. The SEM measurement indicates an obvious breakdown channel through the inside of sample, which provides a convincible evidence for dielectric breakdown. In addition, the impacts of temperature and field on carrier activation and migration are emphasized. Eventually, the non-ohmic conductivity can be explained by the physical phenomenon of dielectric breakdown described by Poole-Frenkel Emission.

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