Abstract
Structural and thermal properties of the two isostructural lanthanide metal-organic frameworks: [Er 2(pdc) 3(dmf) 2]·dmf ( 1) and [Tm 2(pdc) 3(dmf) 2]·dmf ( 2) where pdc = C 5H 3N(COO) 2 2− and dmf = N, N′-dimethylformamide, have been investigated. They are characterized by the BET surface area of 302 and 101 m 2/g for 1 and 2, respectively. This paper deals with the influence of activation conditions on sorption properties of the investigated complexes. Thermal investigations of as-made and activated complexes point to their entirely different thermal decompositions.
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