Abstract
In order to advance the field of single-molecule surface-enhanced Raman scattering (SM-SERS), a better understanding of colloid morphology and hot spot properties in noble metal nanoparticle aggregates is crucial. We present super-resolution optical studies of surface-enhanced Raman scattering (SERS) from rhodamine 6G (R6G) molecules adsorbed onto silver colloid aggregates correlated with scanning electron microscope (SEM) images of those same aggregates. The scattering intensity maps of the SERS signal, obtained from the super-resolution fits, are overlaid with SEM topographical images of the colloids to map the shape of the SERS hot spot and the spatial origin of SERS intensity fluctuations with sub-5 nm resolution. These results have vital implications for developing reproducible and robust substrates capable of SM-SERS.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
