Abstract
To develop high-performance dielectric materials, we report a novel strategy to fabricate core-shell structured BaTiO3@polymer nanoparticles through rotary coating technology combined with a post-treatment bonding process, by using carboxyl-functionalized poly(arylene ether nitrile) (CPAEN) as the polymeric surface-grafting agent. The results demonstrated that the CPAEN was chemically bonded on the surface of BaTiO3 core through monodentate coordination of carboxyl groups, and the BaTiO3 core was completely wrapped by a stable CPAEN shell with a uniform thickness of 4–7 nm. Furthermore, polymer nanocomposites were prepared by using core-shell structured BaTiO3@CPAEN nanoparticles as hybrid nanofillers and poly(arylene ether nitrile) (PAEN) as the polymer matrix. The results indicated that the nanocomposites exhibited enhanced dielectric properties, such as relatively high dielectric permittivity, quite low loss tangent and good permittivity-frequency stability, and excellent thermal stability, high mechanical strength and good flexibility. Therefore, it provides a path to obtain a new class of high-temperature-resistant dielectric materials for various engineering applications.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
