Abstract
Covalent organic framework (COF)-decorated magnetic nanoparticles (Fe3O4@DhaTab) with core-shell structure have been synthesizedby one-pot method. The prepared Fe3O4@DhaTab was well characterized, and parameters ofmagnetic solid-phase extraction (MSPE) for parabens were also investigated in detail. Under optimized conditions, the adsorbent dosage was only 3mg and extraction time was 10min. The developed Fe3O4@DhaTab-based MSPE-HPLC analysis method offered good linearity (0.01-20μgmL-1) with R2 (0.999) and low limits of detection (3.3-6.5μg L-1) using UV detector at 254nm. Theproposed method was applied to determine four parabens in environmental water samples with recoveries in the range64.0-105% and relative standard deviations of 0.16-7.8%. The adsorption mechanism was explored and indicatedthat porous DhaTab shell provided π-π, hydrophobic, and hydrogen bonding interactions in the MSPE process. The results revealed the potential of magnetic-functionalized COFs in determination of environmental contaminants.
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