Core-shell CoFe2O4@Co-Fe-Bi nanoarray: a surface-amorphization water oxidation catalyst operating at near-neutral pH.

Abstract

The exploration of high-performance and earth-abundant water oxidation catalysts operating under mild conditions is highly attractive and challenging. In this communication, core-shell CoFe2O4@Co-Fe-Bi nanoarray on carbon cloth (CoFe2O4@Co-Fe-Bi/CC) was successfully fabricated by in situ surface amorphization of CoFe2O4 nanoarray on CC (CoFe2O4/CC). As a 3D water oxidation electrode, CoFe2O4@Co-Fe-Bi/CC shows outstanding activity with an overpotential of 460 mV to drive a geometrical catalytic current density of 10 mA cm-2 in 0.1 M potassium borate (pH 9.2). Notably, it also demonstrates superior long-term durability for at least 20 h with 96% Faradic efficiency. Density functional theory calculations indicate that the conversion from OOH* to O2 is the rate-limiting step and the high water oxidation activity of CoFe2O4@Co-Fe-Bi/CC is associated with the lower free energy of 1.84 eV on a Co-Fe-Bi shell.