Abstract

The copper(II) complexes formed by the imidazolinone herbicide imazapyr [(±)-2-(4-isopropyl-4-methyl-5-oxo-2-imidazolin-2-yl)nicotinic acid] were studied in aqueous solution by potentiometric and spectroscopic techniques. Imazapyr acts as a chelating molecule and is effective over a wide pH range. The chelating set active in acidic media involves rather weak donors, namely the pyridine and imidazole nitrogens. In neutral media, the lactam site of the imidazolinone ring deprotonates and the ligand takes advantage of a rather basic nitrogen atom, which, assisted by the pyridine donor, yields stable complexes with five-coordination at the metal ion. Keywords: Imazapyr; 2-(4-isopropyl-4-methyl-5-oxo-2-imidazolin-2-yl)nicotinic acid; copper(II) complexes

Full Text
Paper version not known

Talk to us

Join us for a 30 min session where you can share your feedback and ask us any queries you have

Schedule a call

Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.