Abstract
<p indent="0mm">Aromatic amines are widely used in the fields of natural products, pharmaceutical chemistry and materials science, thus the new methods of metal-catalyzed C–N bond coupling for constructing aromatic amines always have always been the focus of attention of chemists and the scientific community. Copper, as a catalyst for the amination of arenes, has attracted extensive attention due to its unique catalytic performance and variety of oxidation states. In this review, the recent progress in the construction of aromatic compounds C(sp<sup>2</sup>)–N catalyzed by copper is reviewed, and the reaction mechanisms of representative amination reactions are briefly described.
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