Abstract
The authors described a copper(I)-catalyzed addition of alkenylzirconocene chloride (AZC) to 3,4-dihydroisoquinoline (DIQ) in the presence of a stoichiometric amount of an acylating reagent. The desired alkenylation-carbamation products were obtained in good yields. Moreover, they have developed the enantioselective addition of the AZD to DIQ using copper(I)/chiral diamine complex, even though moderate enantioselectivity was achieved.
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