Abstract

The use of copper slag as a partial substitute for cement in mortar preparation was studied. Copper slag samples were collected from three dumps in the Atacama Region (Northern Chile). Mortars of 40x40x160 mm (width, height, length) and curing times of 7, 28 and 90 days were used in mechanical testing. Tests were performed with 0% (control mortar), 5, 10, 15 and 20% copper slag as partial replacement of cement. The results of mechanical tests showed a gradual increase in compressive and flexural strength at 7, 28 and 90 days in mortars containing copper slag when compared with the control mortar. The major differences between the control and copper slag mortars are evident after 7 days, which indicates that the presence of slag in the blends has a retardant effect on the hardening process. On the other hand, at 90 days, compressive and flexural strength was very similar for both control mortar and mortars containing copper slag. Optimal compressive and flexural strength values are achieved with 5% of cement substitution by copper slag. The study concludes that the use of copper slag in mortars presents a viable alternative for partial cement replacement, and also contributes to mitigate adverse environmental effects of copper mining.

Highlights

  • Copper slag (CS) is a massive metallurgical waste, and it is recognized as an industrial passive

  • The study concludes that the use of copper slag in mortars presents a viable alternative for partial cement replacement, and contributes to mitigate adverse environmental effects of copper mining

  • Considering that the use of CS from dumps by the construction industry could contribute to improving local environmental conditions, the main objective of this study was to evaluate the mechanical behavior of mortars, using CS from three dumps located in the Atacama region in partial replacement of cement

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Summary

Introduction

Copper slag (CS) is a massive metallurgical waste, and it is recognized as an industrial passive. It is obtained from the transformation of copper ore concentrates into metallic copper in the smelters. Its chemical composition is rich in iron, silicon and aluminum oxides. Slags are deposited in landfills that occupy large areas of land. The main environmental impacts derived from slag disposition are soil usage and visual contamination of landscape. Under certain climatic conditions, leaching may occur depending on the solution characteristics, affecting the original composition and crystalline structure of solid slag (DEMETRIO et al [1])

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