Copper Particle-Enhanced Lithium-Mediated Synthesis of Green Ammonia from Water and Nitrogen.

Abstract

Ammonia (NH3) is one of the most frequently produced chemical products in the world, and it plays an indispensable role in life on Earth. However, its synthesis by the Haber-Bosch (H-B) process is highly energy intensive, resulting in extensive carbon emissions that are unsustainable due to their ability to harm the environment. Herein, we propose a facile and mass-producible strategy for increasing the rate and efficiency of nitrogen fixation through the use of copper particle-catalyzed Li nitridation and a solid electrolyte as a medium to reduce Li salt; the above strategy results in the conversion of water and nitrogen into NH3 through the use of renewable electrical energy at room temperature and atmospheric pressure. Copper particles are uniformly pressed into Li metal by a simple rolling method, and their critical role in accelerating the nitrogen fixation process is revealed by both electrochemical tests and simulations. The nitridation of the Li in the composite is reduced to a few minutes instead of the more than 40 h that are needed for bare Li and N2 at room temperature and atmospheric pressure. Our new method provides three important advantages over the H-B method: (1) the new method can be operated at atmospheric pressure, thereby lowering equipment requirements and increasing security; (2) the use of water instead of fossil fuels as a hydrogen source decreases the consumption of these fuels and the emission of CO2; and (3) the low equipment requirements lead to the ready miniaturization and decentralization of the NH3 synthesizing process, thus promoting the possible use of renewable sources of electricity (e.g., wind or solar energy).