Copper oxide nanofibers obtained by solution blow spinning as catalysts for oxygen evolution reaction

Abstract

In this work, we report copper oxide nanofibers (CuO – N) synthesized by Solution Blow Spinning (SBS) for oxygen evolution reaction (OER), and their comparison with a control sample based on a commercial powder (CuO – C). Both materials were characterized by various techniques, including X-ray diffraction (XRD), magnetometry, scanning electron microscopy (SEM), and spectroscopy (Fourier transform infrared (FT-IR), Raman and X-ray photoelectron (XPS)) to determine the purity, microstructural and surface chemical properties. Subsequently, the performance of copper oxide catalysts in a 1.0 M KOH solution was investigated. Copper oxide with nanofiber morphology (CuO – N) exhibited a small overpotential of 385 mV @ 10 mA cm−2 and a Tafel coefficient of only 76 mV dec−1, i.e., fast kinetics for water splitting, a result that is modulated by oxygen vacancies (O2/O1 = 0.83). The oxygen vacancies are due to the presence of Cu1+ in the lattice. The analyses of the magnetization measurements at 5 K suggest a larger amount of Cu1+ in sample CuO – N. Therefore, this work sheds light on how to design low-cost nanofibrous catalysts based on abundant transition metals in the earth's crust by SBS, an economical and scalable technique, which is promising for energy applications.