Abstract
AbstractA new copper/I2‐catalyzed hydroxyamination of alkenes of unsaturated keto oximes with DMSO as the hydroxy oxygen atom source and medium for assembling 2‐(2‐hydroxyalkyl)‐3,4‐dihydro‐2H‐pyrrole 1‐oxides is described. Mechanistic studies suggest that the reaction is terminated by a single electron oxidation and subsequent nucleophilic reaction.
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