Copper(II) complexes with (2-hydroxybenzyl-2-pyridylmethyl)amine–Hbpa: syntheses, characterization and crystal structures of the ligand and [Cu(II)(Hbpa) 2](ClO 4) 2·2H 2O

Abstract

Copper(II) complexes were synthesized and characterized by means of elemental analysis, IR and visible spectroscopies, EPR and electrochemistry, as well as X-ray structure crystallography. The group consists of discrete mononuclear units with the general formula [Cu(II)(Hbpa) 2](A) 2· nH 2O, where Hbpa=(2-hydroxybenzyl-2-pyridylmethyl)amine and A=ClO 4 −, n=2 ( 1), CH 3COO −, n=3 ( 2), NO 3 −, n=2 ( 3) and SO 4 2−, n=3 ( 4). The structures of the ligand Hbpa and complex 1 have been determined by X-ray crystallography. Complexes 1– 4 have had their UV–Vis spectra measured in both MeCN and DMF. It was observed that the compounds interact with basic solvents, such that molecules coordinate to the metal in axial positions in which phenol oxygen atoms are coordinated in the protonated forms. The ε values were all less than 1000 M −1 cm −1. EPR measurements on powdered samples of 1– 3 gave g ∣∣/ A ∣∣ values between 105 and 135 cm −1, typical for square planar coordination environments. Complex 4·3H 2O exhibits a behaviour typical for tetrahedral coordination. The electrochemical behaviour for complexes 1 and 2 was studied showing irreversible redox waves for both compounds.