Copper(I) sulfide (Cu2S) nanoparticles from Cu(II) diethyldithiocarbamate: Synthesis, characterization and its application in ultrasound-assisted catalytic degradation of organic dye pollutants

Abstract

In this study, copper(I) sulfide (Cu2S) nanoparticles were easily synthesized via thermal decomposition of Cu(II) diethyldithiocarbamate complex at 220°C. Characterization by a variety of spectroscopic and physical techniques confirmed that the obtained product was pure Cu2S composed of about 50nm nanoparticles. An ultrasound-assisted advanced oxidation process (AOP) was developed for the degradation of methylene blue (MB) over the Cu2S nanoparticles. The ultrasound-assisted H2O2/Cu2S catalysis removed 100% MB (25mgL⿿1) in 12min with an apparent rate constant of 0.268min⿿1, which is 193 and 27.5 folds of that in the simple catalytic H2O2/Cu2S and US/H2O2 systems, respectively. The synergistic behavior between Cu2S catalysis and ultrasound waves was demonstrated to be dependent on Cu2S dosage and H2O2 concentration. Trapping experiments indicated that OH radicals were the main reactive species for MB degradation in the present sonocatalytic system. Furthermore, the cycling experiments revealed the good stability of Cu2S nanoparticles.