Abstract
The characteristics of a CuCl-BPC room-temperature molten salt electrolyte and the morphology of the Cu deposits are strongly dependent on CuCl content. It has been assumed that these changes are affected by the ionic species in the melt. Molar fractions of the ionic species were calculated by the simulation method, and their structures computed by ab initio molecular orbital method. The structure deduced from neutron diffraction measurements are consistent with the calculated results.
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