Copper decorated indium oxide rods for photocatalytic CO2 conversion under simulated sun light

Abstract

In this work, copper (Cu) decorated indium oxide (In2O3) rods were prepared via a simple wet chemistry method under mild temperature at atmospheric pressure. The resultant copper decorated indium oxide (Cu/In2O3) composites showed changes in the morphology, composition, crystal property, oxidation status, optical property, and textural surface properties. The In2O3 rods showed highly catalytic efficiency in reducing CO2 to CO, H2 and CH4 in the presence of water via a photocatalytic mechanism under simulated sun light. Incorporation of copper significantly increased the total conversion rates and regulated the selectivity. Total evolution rates of carbon-based products (CO and CH4) for Cu/In2O3 with different Cu content were all greater than 1 mmol·gcat−1·h−1. In addition to the high efficiency, copper addition also enhanced the selectivity towards forming carbon-based products (CH4 and CO), even amounting to 100% for 20% target copper addition. This low-cost preparation method, paired with high CO2 photoreduction efficiency and selectivity, has the potential for future industrial applications of these new Cu/In2O3 composites.