Abstract
AbstractA class of 3‐(azidomethyl)‐2H‐azirine has been obtained through a copper‐catalyzed diazidation of allenes and a subsequent azirination involving vinyl azides. A variety of functional groups in the allenes are well tolerated, providing a series of 3‐(azidomethyl)‐2H‐azirine motifs in 51%‐93% yields (26 examples).
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