Abstract

Polyethylene terephthalate (PET) films of 50 μm thickness were exposed to swift-heavy 50 MeV copper and 84 MeV oxygen ions, with fluence varying from 1 × 1011 to 1 × 1013 ions cm−2. Differential scanning calorimetry (DSC), X-ray diffraction (XRD) and Fourier-transform infrared (FTIR) and UV-visible spectroscopic techniques were used to characterize the irradiated samples. The XRD and DSC analysis indicated the loss of crystallinity during/after the irradiation. The FTIR spectra revealed the formation of alkyne end groups, CC groups and structural deformation with increase of ion fluence. Considerable reduction in the value of the optical bandgap was inferred from the study of the UV-visible absorption curves.

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