Abstract

Copolymers of p-biphenyl acrylate with methyl methacrylate were prepared in methyl ethyl ketone solution at 60° using benzoyl peroxide as initiator. The copolymers were characterized by i.r. and 1H- and 13C-NMR; their compositions were determined by 1H-NMR analysis. The monomer reactivity ratios were determined by application of conventional linearization methods due to Fineman-Ross and Kelen-Tüdös. The molecular weights of the polymers were determined by gel permeation chromatography. Thermogravimetric analyses of the polymers were performed in air.

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