Abstract
The copolymerization of styrene and 1-hexene with the TiCl4-Al(C6H13)3 · Mg(C6H13)2 catalytic system has been investigated. The microstructure of polymer chains, molecular-mass characteristics, and thermophysical properties of the resulting copolymers have been studied. These copolymers contain 15 to 65 mol % styrene and mostly consist of isotactic polystyrene and poly(1-hexene) blocks.
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