Abstract

The spontaneous and initiated copolymerizations of 2-substituted 2-oxazolines carrying donor ( N-carbazolyl and 9-anthryl) and acceptor (3,5-dinitrophenyl) pendant groups, in bulk or in solution have been investigated. The copolymers possess intramolecular charge transfer complexes properties due to both the complexing of pendant electroactive groups (π-π type complex) as well as to internal complexing of the lone pair of electrons of the nitrogen atoms from the polyethylenimine chain with 3,5-dinitrophenyl acceptor groups (π-π type complex).

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