Abstract
AbstractActivation parameters were determined for the exchange between the two types of carboxylate groups which are cis and trans to the VO bonds in the bis(oxalato)dioxovanadate(V) ion, [VO2(C2O4)2]3−. Kinetic data were obtained from the 13C NMR spectra at eleven temperatures between 268 and 306 K by the total line‐shape method. The coordination‐site exchange mechanism, involving chelate ring opening and closing in the ion, is proposed. The solid‐state 13C NMR spectra of the oxalato complexes, (NH4)3[VO2(C2O4)2]·2H2O and K3[VO2(C2O4)2]·3H2O, are also discussed in relation to the structures.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
