Abstract
Voronoi–Dirichlet polyhedra (VDP) and the method of intersecting spheres were used to perform crystal-chemical analyses of compounds containing complexes [Rh a X n ] z– (X = F, Cl, Br). It was found that, irrespective of oxidation number (+3, +4, or +5), rhodium atoms always exhibit the coordination number 6 with respect to the halogen atoms and have octahedral coordination. The influence of site symmetry and the valence state of Rh on the distortion of RhX6 octahedra are considered. The electronic configuration of the Rh atoms is shown to influence the symmetry of their valence-force field within the crystal structure.
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