Abstract
AbstractThis paper reviews various coordination/ organometallic polymers in which the metal atoms are incorporated in the backbone using diphosphine and diisocyanide ligands. Such ligands includes diphosphines of the type bis(diphenylphosphino)alkane where alkane is (CH2)m with m = 1, 3‐6, bis(diphenylphosphino)acetylene (dpa), and bis(dimethylphosphino)methane (dmpm), and diisocyanides such as 1,8‐diiso‐cyano‐p‐menthane (dmb) and p‐diisocyanotetra‐methylbenzene (ditmb). The metal fragments are monocations such as Cu+, Ag+, and Au+, dinuclear species such as Pd2(dmb)22+, Pd2(dppm)22+, M2(dmpm)32+ (M = Cu, Ag), and clusters such as M4(dmb)42+ (M = Pd, Pt).
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