Abstract
Abstract The coordination process of NH3 and C2H4 onto “naked” W(CO)5, having one coordinatively unsaturated site, was investigated using a laser-based time-resolved infrared absorption spectroscopy in the gas phase. W(CO)5, selectively prepared by a pulsed 355-nm laser photolysis of W(CO)6, was observed to react with either reactant gas L to make a simple coordination complex, W(CO)5(L), where L is NH3 or C2H4.
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