Abstract
Bond activation of small molecules through coordination to low valent metal complexes in M⋯X-H type interactions (where X = O, N, B, Si, etc.) leads to the formation of unusually weak X-H bonds and provides a powerful approach for the synthesis of target compounds under very mild conditions. Coordination of small molecules like water, amides, silanes, boranes, and dinitrogen to Ti(III) or Ti(II) complexes results in the synergetic redistribution of electrons between the metal orbitals and the ligand orbitals which weakens and enables the facile cleavage of the X-H or N-N bonds of the ligands. This review presents an overview of coordination-induced bond activation of small molecules by low valent titanium complexes. In particular, the applications of low valent titanium-induced bond weakening in nitrogen fixation are presented. The review concludes with potential future directions for work in this area including low-valent Ti-based PCET systems, photocatalytic nitrogen reduction, and approaches to tailoring complexes for optimal bond activation.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.