Abstract
One-dimensional (1D) metal-organic frameworks (MOFs) have shown great potential for designing more sensitive and smart stimuli-responsive photoluminescence metal-organic frameworks (PL-MOFs). Herein, we propose a strategy for constructing the 1D MOFs with tunable stimuli-responsive luminescence regions based on coordination-guided conformational locking. Two flexible 1D MOF microcrystals with trans- and cis-coordination modes, respectively, were synthesized by controlling the spatial constraint of solvents. The two 1D frameworks possess different conformation lockings of gain ligands, which have a great influence on the rotating restrictions and corresponding excited-state behaviors, generating the remarkably distinct color-tunable ranges (cyan-blue to green and cyan-blue to yellow, respectively). On this basis, the two 1D MOF materials, benefiting from the varied stimuli-responsive ranges, have displayed great potential in fulfilling the anticounterfeiting and information encryption applications. These results provide valuable guidance for the development of smart MOF-based stimuli-responsive materials in information identification and data encryption.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
